Cu-MOF modified ZnIn2S4 nanosheet composite catalyst for photocatalytic hydrogen production
Haifei Chen,
Jing Wu,
Yuwei Zhu,
Jie Yang,
Bo Tang,
Tao Zhang and
Huihang Yang
Renewable Energy, 2024, vol. 228, issue C
Abstract:
In the realm of photocatalysis, the creation of clean and pollution-free composite material catalysts is critical. Electrostatic self-assembly techniques were used in this study to construct ZnIn2S4 nanosheets onto the surface of Cu-MOF, culminating in the development of a unique Cu-MOF/ZnIn2S4 composite catalyst. Cu-MOF was shown to have a strong interface impact with ZnIn2S4, which resulted in a large increase in the number of active sites and, consequently, the efficiency of hydrogen generation. This was demonstrated by a number of parameters. The Cu-MOF/ZnIn2S4-10 composite material's optimum hydrogen evolution rate was 0.3 mmol h−1g−1, which was 2.14 times larger than that of pure ZnIn2S4 nanosheets (0.14 mmol h−1g−1). Furthermore, the development of Cu-MOF/ZnIn2S4 heterojunctions considerably improved ZnIn2S4's deficiencies in photocatalytic hydrogen production, increasing charge separation rates and providing a viable approach to improve ZnIn2S4's hydrogen production efficiency.
Keywords: Cu-MOF/ZnIn2S4 composite material; Electrostatic self-assembly; Photocatalytic hydrogen production; Metal-Organic framework (search for similar items in EconPapers)
Date: 2024
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Persistent link: https://EconPapers.repec.org/RePEc:eee:renene:v:228:y:2024:i:c:s0960148124007407
DOI: 10.1016/j.renene.2024.120672
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