Hierarchical HZSM-5 catalysts enhancing monocyclic aromatics selectivity in co-pyrolysis of wheat straw and polyethylene mixture

Hong Tian, Rui Zhu, Guangming Zhu, Jiawei Wang and Yi Cheng

Renewable Energy, 2024, vol. 233, issue C

Abstract: The limitation in bio-oil quality hampers its further utilization in the fuel or chemical industry. This study employed a combination of tetra propylammonium hydroxide (TPAOH) and NaOH solutions for HZSM-5 desilication to enhance the yield of monocyclic aromatic hydrocarbons in the catalytic co-pyrolysis of wheat straw with polyethylene. Results revealed hierarchical HZSM-5, prepared with equal mole concentrations of NaOH and TPAOH, exhibited optimal catalytic performance. The bio-oil from this process had an aromatic content of 72 %, with monocyclic aromatic hydrocarbons (MAHs) constituting 56.26 %. Further optimization was achieved through iron modification of hierarchical HZSM-5. The addition of 0.5 % iron-modified hierarchical HZSM-5 increased the aromatic hydrocarbons to 80.57 %, with BTX compounds (benzene, toluene, and xylene) reaching a selectivity of 61.9 %. This approach reduced polycyclic aromatic hydrocarbons (PAHs), contributing to less coke formation, presenting a promising method for high-quality bio-oil.

Keywords: Biomass and plastic; Catalytic co-pyrolysis; Hierarchical HZSM-5; Iron modification; Monocyclic aromatic hydrocarbons (search for similar items in EconPapers)
Date: 2024
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Persistent link: https://EconPapers.repec.org/RePEc:eee:renene:v:233:y:2024:i:c:s0960148124012187

DOI: 10.1016/j.renene.2024.121150

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