Effects of ionic liquid mixtures on lipid extraction from Chlorella vulgaris

Sun-A Choi, You-Kwan Oh, Min-Ji Jeong, Seung Wook Kim, Jin-Suk Lee and Ji-Yeon Park

Renewable Energy, 2014, vol. 65, issue C, 169-174

Abstract: In this study, pre-biodiesel-production lipid extraction from microalgae (Chlorella vulgaris) was performed. The yield-enhancing effects of ionic liquid blends on the lipid extraction were investigated. The initial fatty acids content of the C. vulgaris was 292.2 mg/g cell. The lipid extraction yield using single ionic liquids was compared with the yield obtained with organic solvents and ionic liquid mixtures, respectively. The yield by hexane–methanol solvent was 185.4 mg/g cell. Among the 12 ionic liquids, 1-ethyl-3-methyl imidazolium acetate, 1-ethyl-3-methyl imidazolium diethylphosphate, 1-ethyl-3-methyl imidazolium tetrafluoroborate, and 1-ethyl-3-methyl imidazolium chloride showed high (>200.0 mg/g cell) lipid extraction yields. Although the yields of 1-ethyl-3-methyl imidazolium ethyl sulfate and 1-ethyl-3-methyl imidazolium thiocyanate were only 60.5 and 42.7 mg/g cell, respectively, the yield for their mixture (weight ratio of 1:1) was improved to 158.2 mg/g cell. Similarly, whereas the lipid extraction yield of 1-ethyl-3-methyl imidazolium hydrogen sulfate was just 35.2 mg/g cell, that for its mixture with 1-ethyl-3-methyl imidazolium thiocyanate (weight ratio of 1:1) was boosted to 200.6 mg/g cell. Overall, the synergistic effects of the ionic liquid mixtures with different anions improved the lipid extraction yield of C. vulgaris.

Keywords: Lipid extraction; Chlorella vulgaris; Microalgal oil; Ionic liquid mixtures; 1-Ethyl-3-methyl imidazolium cation (search for similar items in EconPapers)
Date: 2014
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Citations: View citations in EconPapers (11)

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Persistent link: https://EconPapers.repec.org/RePEc:eee:renene:v:65:y:2014:i:c:p:169-174

DOI: 10.1016/j.renene.2013.08.015

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