Lanthanum-Modified Phosphogypsum Red Mud Composite for the Co-Adsorption of Cadmium and Arsenic: Mechanism Study and Soil Remediation

Chengmei Shang, Zhixi Geng, Yuanyuan Sun (), Dongxue Che, Qingjiao Zhao, Ting Chen, Ming Tang and Lijuan Huo ()
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Chengmei Shang: School of Life Sciences, Guizhou Normal University, Guiyang 550001, China
Zhixi Geng: Beijing Zhongnong Jiayuan Eco-Engineering Technology Co., Ltd., Beijing 100043, China
Yuanyuan Sun: School of Life Sciences, Guizhou Normal University, Guiyang 550001, China
Dongxue Che: School of Life Sciences, Guizhou Normal University, Guiyang 550001, China
Qingjiao Zhao: School of Life Sciences, Guizhou Normal University, Guiyang 550001, China
Ting Chen: School of Life Sciences, Guizhou Normal University, Guiyang 550001, China
Ming Tang: School of Life Sciences, Guizhou Normal University, Guiyang 550001, China
Lijuan Huo: School of Environment and Resources, Taiyuan University of Science and Technology, Taiyuan 030024, China

Agriculture, 2024, vol. 14, issue 3, 1-23

Abstract: With the development of industrial activities and the agricultural and mining industries, farmland soils are facing serious problems related to heavy metal contamination, especially cadmium (Cd) and arsenic (As) contamination. In this study, two industrial by-products, phosphogypsum (PG) and red mud (RM), were modified by lanthanum (La) impregnation to form a new composite (L-PR) to investigate the adsorption performance of Cd(II)/As(V) in both single and binary systems. The adsorption mechanisms of Cd(II)/As(V) on L-PR were analyzed using SEM, XRD, FTIR, and XPS. The passivation effect of L-PR on the Cd-As composite contaminated soil was confirmed through a soil cultivation experiment. The adsorption experiments revealed that L-PR showed superior adsorption capabilities for Cd(II) and As(V) compared to PG and RM. Additionally, L-PR was found to be less affected by changes in pH. The kinetic studies indicated that Cd(II) and As(V) adsorption by L-PR followed the second-order kinetic model most accurately. Isothermal adsorption experiments revealed that the adsorption of Cd(II) by L-PR was more in accordance with the Freundlich model, while As(V) was more in accordance with the Langmuir model. The mechanisms of Cd(II) and As(V) adsorption on L-PR involved electrostatic attraction, ion exchange, complexation, and precipitation. The adsorption of Cd(II) is dominated by complexation and precipitation, and the adsorption of As(V) is dominated by ion exchange and complexation. Soil cultivation experiments showed that L-PR significantly reduced the available Cd and As concentrations in soil by 86.01% and 27.80%, respectively, and it could induce the transformation of non-stable Cd(II)/As(V) to the more stable residual. In summary, L-PR exhibits facile preparation, excellent adsorption performance, and is capable of simultaneously removing Cd(II) and As(V) from aqueous solutions while immobilizing these contaminants in soil. These remarkable attributes made it a highly promising alternative for the simultaneous treatment of various toxic metal contaminants.

Keywords: industrial by-products; lanthanum; cadmium; arsenic; adsorption (search for similar items in EconPapers)
JEL-codes: Q1 Q10 Q11 Q12 Q13 Q14 Q15 Q16 Q17 Q18 (search for similar items in EconPapers)
Date: 2024
References: View complete reference list from CitEc
Citations: View citations in EconPapers (1)

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