Biochar for Soil Fertility and Climate Mitigation: Review on Feedstocks, Pyrolysis Conditions, Functional Properties, and Applications with Emerging AI Integration

Florian Marin, Oana Maria Tanislav, Marius Constantinescu, Antoaneta Roman, Felicia Bucura, Simona Oancea and Anca Maria Zaharioiu ()
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Florian Marin: National Research and Development Institute for Cryogenic and Isotopic Technologies—ICSI, 4th Uzinei Street, 240050 Ramnicu Valcea, Romania
Oana Maria Tanislav: National Research and Development Institute for Cryogenic and Isotopic Technologies—ICSI, 4th Uzinei Street, 240050 Ramnicu Valcea, Romania
Marius Constantinescu: National Research and Development Institute for Cryogenic and Isotopic Technologies—ICSI, 4th Uzinei Street, 240050 Ramnicu Valcea, Romania
Antoaneta Roman: National Research and Development Institute for Cryogenic and Isotopic Technologies—ICSI, 4th Uzinei Street, 240050 Ramnicu Valcea, Romania
Felicia Bucura: National Research and Development Institute for Cryogenic and Isotopic Technologies—ICSI, 4th Uzinei Street, 240050 Ramnicu Valcea, Romania
Simona Oancea: Faculty of Agricultural Sciences, Food Industry and Environmental Protection, “Lucian Blaga” University of Sibiu, 7-9 I. Ratiu Street, 550012 Sibiu, Romania
Anca Maria Zaharioiu: National Research and Development Institute for Cryogenic and Isotopic Technologies—ICSI, 4th Uzinei Street, 240050 Ramnicu Valcea, Romania

Agriculture, 2025, vol. 15, issue 22, 1-25

Abstract: Soil degradation, declining fertility, and rising greenhouse gas emissions highlight the urgent need for sustainable soil management strategies. Among them, biochar has gained recognition as a multifunctional material capable of enhancing soil fertility, sequestering carbon, and valorizing biomass residues within circular economy frameworks. This review synthesizes evidence from 186 peer-reviewed studies to evaluate how feedstock diversity, pyrolysis temperature, and elemental composition shape the agronomic and environmental performance of biochar. Crop residues dominated the literature (17.6%), while wood, manures, sewage sludge, and industrial by-products provided more targeted functionalities. Pyrolysis temperature emerged as the primary performance driver: 300–400 °C biochars improved pH, cation exchange capacity (CEC), water retention, and crop yield, whereas 450–550 °C biochars favored stability, nutrient concentration, and long-term carbon sequestration. Elemental composition averaged 60.7 wt.% C, 2.1 wt.% N, and 27.5 wt.% O, underscoring trade-offs between nutrient supply and structural persistence. Greenhouse gas (GHG) outcomes were context-dependent, with consistent Nitrous Oxide (N 2 O) reductions in loam and clay soils but variable CH 4 responses in paddy systems. An emerging trend, present in 10.6% of studies, is the integration of artificial intelligence (AI) to improve predictive accuracy, adsorption modeling, and life-cycle assessment. Collectively, the evidence confirms that biochar cannot be universally optimized but must be tailored to specific objectives, ranging from soil fertility enhancement to climate mitigation.

Keywords: biochar; soil fertility; carbon sequestration; pyrolysis; greenhouse gas mitigation; waste valorization; AI (search for similar items in EconPapers)
JEL-codes: Q1 Q10 Q11 Q12 Q13 Q14 Q15 Q16 Q17 Q18 (search for similar items in EconPapers)
Date: 2025
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