Pyrolysis Kinetics of Physical Components of Wood and Wood-Polymers Using Isoconversion Method

Wenjia Jin, Kaushlendra Singh and John Zondlo
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Wenjia Jin: Division of Forestry and Natural Resources, West Virginia University, Morgantown, WV 26506, USA
Kaushlendra Singh: Division of Forestry and Natural Resources, West Virginia University, Morgantown, WV 26506, USA
John Zondlo: Chemical Engineering, West Virginia University, Morgantown, WV 26506, USA

Agriculture, 2013, vol. 3, issue 1, 1-21

Abstract: Two hardwood species, namely red oak and yellow-poplar, were separated into their bark, sapwood and heartwood components. The samples were tested for calorific value, specific gravity, proximate analysis, mineral composition, chemical composition, ultimate analysis, and thermo-chemical decomposition behavior. In addition, the thermo-chemical decomposition behaviors of cellulose, xylan, and lignin polymers were also tested. Thermo-chemical decomposition behavior was assessed using a thermo-gravimetric (TGA) system by heating the sample from 50 °C to 700 °C at the heating rates of 10, 30 and 50 °C/min under nitrogen. The activation energy was calculated for various fractional conversion values using the isoconversion method. The results showed that char yields of lignin, cellulose and xylan were 41.43%, 4.45% and 1.89%, respectively, at the end of pyrolysis. Furthermore, cellulose, xylan and lignin decomposed dramatically in the temperature range of 320 °C to 360 °C, 150 °C to 230 °C and 100 °C to 410 °C, respectively, with decomposition peaks occurring at 340 °C, 200 °C and 340 °C, respectively. In addition, the maximum activation energy for cellulose was 381 kJ/mol at 360 °C and for xylan it was 348 kJ/mol at 210 °C.

Keywords: bioenergy; torrefaction; hardwood components; activation energy (search for similar items in EconPapers)
JEL-codes: Q1 Q10 Q11 Q12 Q13 Q14 Q15 Q16 Q17 Q18 (search for similar items in EconPapers)
Date: 2013
References: View references in EconPapers View complete reference list from CitEc
Citations: View citations in EconPapers (8)

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