Hydrothermal growth of diamond in metal–C–H2O systems

Xing-Zhong Zhao, Rustum Roy, Kuruvilla A. Cherian and Andrzej Badzian
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Xing-Zhong Zhao: The Pennsylvania State University
Rustum Roy: The Pennsylvania State University
Kuruvilla A. Cherian: The Pennsylvania State University
Andrzej Badzian: The Pennsylvania State University

Nature, 1997, vol. 385, issue 6616, 513-515

Abstract: Abstract The first report of synthetic diamond involved a high-pressure high-temperature (HPHT) process in which diamond was the thermodynamically stable phase1. Subsequent attempts to make diamond at less extreme conditions culminated in the rapid growth of diamond films by chemical vapour deposition2,3. But the question of whether diamond might be grown in hydrothermal conditions mimicking those under which it is formed in the Earth has been long debated4–6. It seems reasonable to suppose that metals might play a catalytic or solubilizing role in this context, given their role in the HPHT method1, in a recent low-pressure solid-state synthetic approach7 and in the recrystallization of diamond in the Ni–NaOH–C system8. Hydrothermal synthesis of diamond has been explored at some length9–13, but with equivocal results. Here we report evidence from spectro-scopic, diffraction and microscopic techniques which suggest that aggregates, tens of micrometres in size, of small diamond crystals can be grown in a hydrothermal environment from a mixture of carbon, water and metal (usually pure nickel). Crucially, we have been able to distinguish new diamond from the diamond seeds added to nucleate new growth.

Date: 1997
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DOI: 10.1038/385513a0

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