Experimental verification of the quasi-unit-cell model of quasicrystal structure

Paul J. Steinhardt (), H.-C. Jeong, K. Saitoh, M. Tanaka, E. Abe and A. P. Tsai
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Paul J. Steinhardt: Princeton University
H.-C. Jeong: Sejong University
K. Saitoh: Research Institute for Scientific Measurements, Tohoku University
M. Tanaka: Research Institute for Scientific Measurements, Tohoku University
E. Abe: National Research Institute for Metals
A. P. Tsai: National Research Institute for Metals

Nature, 1998, vol. 396, issue 6706, 55-57

Abstract: Abstract The atomic structure of quasicrystals1 — solids with long-range order, but non-periodic atomic lattice structure — is often described as the three-dimensional generalization of the planar two-tile Penrose pattern2. Recently, an alternative model has been proposed3,4,5 that describes such structures in terms of a single repeating unit3,4,5 — the three-dimensional generalization of a pattern composed of identical decagons. This model is similar in concept to the unit-cell description of periodic crystals, with the decagon playing the role of a ‘quasi-unit cell’. But, unlike the unit cells in periodic crystals, these quasi-unit cells overlap their neighbours, in the sense that they share atoms. Nevertheless, the basic concept of unit cells in both periodic crystals and quasicrystals is essentially the same: solving the entire atomic structure of the solid reduces to determining the distribution of atoms in the unit cell. Here we report experimental evidence for the quasi-unit-cell model by solving the structure of the decagonal quasicrystal Al72Ni20Co8. The resulting structure is consistent with images obtained by electron and X-ray diffraction, and agrees with the measured stoichiometry, density and symmetry of the compound. The quasi-unit-cell model provides a significantly better fit to these results than all previous alternative models, including Penrose tiling.

Date: 1998
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DOI: 10.1038/23902

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