Epitaxial self-assembly of block copolymers on lithographically defined nanopatterned substrates

Sang Ouk Kim, Harun H. Solak, Mark P. Stoykovich, Nicola J. Ferrier, Juan J. de Pablo and Paul F. Nealey ()
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Sang Ouk Kim: University of Wisconsin
Harun H. Solak: Paul Scherrer Institute
Mark P. Stoykovich: University of Wisconsin
Nicola J. Ferrier: University of Wisconsin
Juan J. de Pablo: University of Wisconsin
Paul F. Nealey: University of Wisconsin

Nature, 2003, vol. 424, issue 6947, 411-414

Abstract: Abstract Parallel processes for patterning densely packed nanometre-scale structures are critical for many diverse areas of nanotechnology. Thin films of diblock copolymers1,2,3,4,5,6,7,8,9,10,11 can self-assemble into ordered periodic structures at the molecular scale (∼5 to 50 nm), and have been used as templates to fabricate quantum dots1,2, nanowires3,4,5, magnetic storage media6, nanopores7 and silicon capacitors8. Unfortunately, perfect periodic domain ordering can only be achieved over micrometre-scale areas at best12,13 and defects exist at the edges of grain boundaries. These limitations preclude the use of block-copolymer lithography for many advanced applications14. Graphoepitaxy12,15, in-plane electric fields3,16, temperature gradients17, and directional solidification14,18 have also been demonstrated to induce orientation or long-range order with varying degrees of success. Here we demonstrate the integration of thin films of block copolymer with advanced lithographic techniques to induce epitaxial self-assembly of domains. The resulting patterns are defect-free, are oriented and registered with the underlying substrate and can be created over arbitrarily large areas. These structures are determined by the size and quality of the lithographically defined surface pattern rather than by the inherent limitations of the self-assembly process. Our results illustrate how hybrid strategies to nanofabrication allow for molecular level control in existing manufacturing processes.

Date: 2003
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DOI: 10.1038/nature01775

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