Low-temperature processing of ‘baroplastics’ by pressure-induced flow

Juan A. Gonzalez-Leon, Metin H. Acar, Sang-Woog Ryu, Anne-Valérie G. Ruzette and Anne M. Mayes ()
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Juan A. Gonzalez-Leon: Massachusetts Institute of Technology
Metin H. Acar: Massachusetts Institute of Technology
Sang-Woog Ryu: Massachusetts Institute of Technology
Anne-Valérie G. Ruzette: Massachusetts Institute of Technology
Anne M. Mayes: Massachusetts Institute of Technology

Nature, 2003, vol. 426, issue 6965, 424-428

Abstract: Abstract The manufacturing of plastics traditionally involves melt processing at temperatures typically greater than 200 °C—to enable extrusion or moulding under pressure into desired forms—followed by solidification. This process consumes energy and can cause substantial degradation of polymers and additives (such as flame retardants and ultraviolet stabilizers), limiting plastics performance and recyclability1. It was recently reported that the application of pressure could induce melt-like behaviour in the block copolymer polystyrene-block-poly(n-butyl methacrylate) (PS-b-PBMA)2, and this behaviour has now been demonstrated in a range of other block copolymer systems3,4,5,6,7,8. These polymers have been termed baroplastics2,3,4,5. However, in each case, the order-to-disorder transition, which gives rise to the accompanying change in rheology from soft solid to melt9,10, was observed at temperatures far exceeding the glass transition temperatures (Tg) of both components. Here we show that baroplastic systems containing nanophase domains of one high-Tg and one low-Tg component can exhibit melt-like flow under pressure at ambient temperature through an apparent semi-solid partial mixing mechanism that substantially preserves the high-Tg phase. These systems were shredded and remoulded ten times with no evident property degradation. Baroplastics with low-temperature formability promise lower energy consumption in manufacture and processing, reduced use of additives, faster production and improved recyclability, and also provide potential alternatives to current thermoplastic elastomers, rubber-modified plastics, and semi-crystalline polymers11,12.

Date: 2003
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DOI: 10.1038/nature02140

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