Reduction of hysteresis losses in the magnetic refrigerant Gd5Ge2Si2 by the addition of iron

Virgil Provenzano (), Alexander J. Shapiro and Robert D. Shull
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Virgil Provenzano: Magnetic Materials Group, NIST
Alexander J. Shapiro: Magnetic Materials Group, NIST

Nature, 2004, vol. 429, issue 6994, 853-857

Abstract: Abstract The magnetocaloric effect is the change in temperature of a material as a result of the alignment of its magnetic spins that occurs on exposure to an external magnetic field. The phenomenon forms the basis for magnetic refrigeration, a concept purported to be more efficient and environmentally friendly than conventional refrigeration systems1,2,3,4,5. In 1997, a ‘giant’ magnetocaloric effect, between 270 K and 300 K, was reported in Gd5Ge2Si2, demonstrating its potential as a near-room-temperature magnetic refrigerant6,7,8. However, large hysteretic losses (which make magnetic refrigeration less efficient) occur in the same temperature range8,9. Here we report the reduction (by more than 90 per cent) of these hysteretic losses by alloying the compound with a small amount of iron. This has the additional benefit of shifting the magnetic entropy change peak (a measure of the refrigerator's optimal operating temperature) from 275 K to 305 K, and broadening its width. Although the addition of iron does not significantly affect the refrigerant capacity of the material, a greater net capacity is obtained for the iron-containing alloy when the hysteresis losses are accounted for. The iron-containing alloy is thus a much-improved magnetic refrigerant for near-room-temperature applications.

Date: 2004
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DOI: 10.1038/nature02657

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