Ionic colloidal crystals of oppositely charged particles

Mirjam E. Leunissen (), Christina G. Christova, Antti-Pekka Hynninen, C. Patrick Royall, Andrew I. Campbell, Arnout Imhof, Marjolein Dijkstra, René van Roij and Alfons van Blaaderen ()
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Mirjam E. Leunissen: Utrecht University
Christina G. Christova: Utrecht University
Antti-Pekka Hynninen: Utrecht University
C. Patrick Royall: Utrecht University
Andrew I. Campbell: Utrecht University
Arnout Imhof: Utrecht University
Marjolein Dijkstra: Utrecht University
René van Roij: Utrecht University
Alfons van Blaaderen: Utrecht University

Nature, 2005, vol. 437, issue 7056, 235-240

Abstract: Abstract Colloidal suspensions are widely used to study processes such as melting, freezing1,2,3 and glass transitions4,5. This is because they display the same phase behaviour as atoms or molecules, with the nano- to micrometre size of the colloidal particles making it possible to observe them directly in real space3,4. Another attractive feature is that different types of colloidal interactions, such as long-range repulsive1,3, short-range attractive5, hard-sphere-like2,3,4 and dipolar3, can be realized and give rise to equilibrium phases. However, spherically symmetric, long-range attractions (that is, ionic interactions) have so far always resulted in irreversible colloidal aggregation6. Here we show that the electrostatic interaction between oppositely charged particles can be tuned such that large ionic colloidal crystals form readily, with our theory and simulations confirming the stability of these structures. We find that in contrast to atomic systems, the stoichiometry of our colloidal crystals is not dictated by charge neutrality; this allows us to obtain a remarkable diversity of new binary structures. An external electric field melts the crystals, confirming that the constituent particles are indeed oppositely charged. Colloidal model systems can thus be used to study the phase behaviour of ionic species. We also expect that our approach to controlling opposite-charge interactions will facilitate the production of binary crystals of micrometre-sized particles, which could find use as advanced materials for photonic applications7.

Date: 2005
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DOI: 10.1038/nature03946

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