Enantioselective halocyclization of polyprenoids induced by nucleophilic phosphoramidites

Akira Sakakura, Atsushi Ukai and Kazuaki Ishihara ()
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Akira Sakakura: Graduate School of Engineering, Nagoya University, Furo-cho, Chikusa, Nagoya 464-8603, Japan
Atsushi Ukai: Graduate School of Engineering, Nagoya University, Furo-cho, Chikusa, Nagoya 464-8603, Japan
Kazuaki Ishihara: Graduate School of Engineering, Nagoya University, Furo-cho, Chikusa, Nagoya 464-8603, Japan

Nature, 2007, vol. 445, issue 7130, 900-903

Abstract: This paper reports the synthesis of simple polyprenoids through a halocyclization reaction that used a nucleophilic promoter. This enabled halogenated cyclic products in high yields and enantiomeric purity to be obtained.

Date: 2007
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DOI: 10.1038/nature05553

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