Infinite-layer iron oxide with a square-planar coordination

Y. Tsujimoto, C. Tassel, N. Hayashi, T. Watanabe, H. Kageyama (), K. Yoshimura, M. Takano, M. Ceretti, C. Ritter and W. Paulus
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Y. Tsujimoto: Graduate School of Science, Kyoto University, Sakyo, Kyoto 606-8502, Japan
C. Tassel: Graduate School of Science, Kyoto University, Sakyo, Kyoto 606-8502, Japan
N. Hayashi: Graduate School of Human and Environmental Studies, Kyoto University, Sakyo, Kyoto 606-8501, Japan
T. Watanabe: Graduate School of Science, Kyoto University, Sakyo, Kyoto 606-8502, Japan
H. Kageyama: Graduate School of Science, Kyoto University, Sakyo, Kyoto 606-8502, Japan
K. Yoshimura: Graduate School of Science, Kyoto University, Sakyo, Kyoto 606-8502, Japan
M. Takano: Institute for Chemical Research, Kyoto University, Uji, Kyoto 611-0011, Japan
M. Ceretti: University of Rennes 1, Sciences Chimiques de Rennes UMR CNRS 6226, Campus de Beaulieu Bâtiment 10B
C. Ritter: Institute Laue Langevin, BP 156, 38042, Grenoble, France
W. Paulus: University of Rennes 1, Sciences Chimiques de Rennes UMR CNRS 6226, Campus de Beaulieu Bâtiment 10B

Nature, 2007, vol. 450, issue 7172, 1062-1065

Abstract: The synthesis of SrFeO2, a new compound bearing a square-planar oxygen coordination around Fe2+, is shown. SrFeO2 is isostructural with 'infinite layer' cupric oxides, and exhibits a magnetic order far above room temperature.

Date: 2007
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DOI: 10.1038/nature06382

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