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Magnetic assembly of colloidal superstructures with multipole symmetry

Randall M. Erb, Hui S. Son, Bappaditya Samanta, Vincent M. Rotello and Benjamin B. Yellen ()
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Randall M. Erb: Duke University, Center for Biologically Inspired Materials and Material Systems, Box 90300, Hudson Hall, Durham, North Carolina 27708, USA
Hui S. Son: Duke University, Center for Biologically Inspired Materials and Material Systems, Box 90300, Hudson Hall, Durham, North Carolina 27708, USA
Bappaditya Samanta: University of Massachusetts, Amherst, Massachusetts 01003, USA
Vincent M. Rotello: University of Massachusetts, Amherst, Massachusetts 01003, USA
Benjamin B. Yellen: Duke University, Center for Biologically Inspired Materials and Material Systems, Box 90300, Hudson Hall, Durham, North Carolina 27708, USA

Nature, 2009, vol. 457, issue 7232, 999-1002

Abstract: A flowering of colloids The controlled assembly of complex structures from simple colloidal building blocks can produce materials with properties useful in photonics, as biological sensors and elsewhere. A new method of assembling complex colloidal structures in bulk fluid by applying a magnetic field to a mixture of colloidal particles of different size, magnetization and composition is now reported. The shapes that can be obtained when these particles are suspended in a ferromagnetic fluid resemble electric charge distributions such as quadrupoles and octupoles, generating a variety of complex structures including ring- and flower-shaped assemblies. The repulsion that exists between two assembled particles also prevents the formation of clusters.

Date: 2009
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DOI: 10.1038/nature07766

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