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The ITQ-37 mesoporous chiral zeolite

Junliang Sun, Charlotte Bonneau, Ángel Cantín, Avelino Corma (), María J. Díaz-Cabañas, Manuel Moliner, Daliang Zhang, Mingrun Li and Xiaodong Zou ()
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Junliang Sun: Structural Chemistry and Berzelii Centre, EXSELENT on Porous Materials, Stockholm University, SE-106 91, Stockholm, Sweden
Charlotte Bonneau: Structural Chemistry and Berzelii Centre, EXSELENT on Porous Materials, Stockholm University, SE-106 91, Stockholm, Sweden
Ángel Cantín: Instituto de Tecnología Química (UPV-CSIC), Av. Naranjos s/n, E-46022 Valencia, Spain
Avelino Corma: Instituto de Tecnología Química (UPV-CSIC), Av. Naranjos s/n, E-46022 Valencia, Spain
María J. Díaz-Cabañas: Instituto de Tecnología Química (UPV-CSIC), Av. Naranjos s/n, E-46022 Valencia, Spain
Manuel Moliner: Instituto de Tecnología Química (UPV-CSIC), Av. Naranjos s/n, E-46022 Valencia, Spain
Daliang Zhang: Structural Chemistry and Berzelii Centre, EXSELENT on Porous Materials, Stockholm University, SE-106 91, Stockholm, Sweden
Mingrun Li: Structural Chemistry and Berzelii Centre, EXSELENT on Porous Materials, Stockholm University, SE-106 91, Stockholm, Sweden
Xiaodong Zou: Structural Chemistry and Berzelii Centre, EXSELENT on Porous Materials, Stockholm University, SE-106 91, Stockholm, Sweden

Nature, 2009, vol. 458, issue 7242, 1154-1157

Abstract: Something big in zeolites Zeolites, microporous aluminosilciates with a cage-like framework, are industrially important in catalysis and separation. The bigger the pore size that can be achieved in a zeolite, the bigger and more complex the reactant molecules that can be accommodated for catalytic or other purposes. A new zeolite landmark is reported in this issue, the synthesis of ITQ-37, a new germanosilicate zeolite with the largest pores to date, about 25 Å across. Materials with pores of this size have previously been mostly amorphous. ITQ-37 has a single-channel system, so that the pores are readily accessible, and has chiral pores, useful for the separation of enantiomorphic molecules.

Date: 2009
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DOI: 10.1038/nature07957

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