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Pleats in crystals on curved surfaces

William T. M. Irvine (), Vincenzo Vitelli and Paul M. Chaikin ()
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William T. M. Irvine: Center for Soft Matter Research, New York University, 4 Washington Place, New York, New York 10003, USA
Vincenzo Vitelli: Instituut-Lorentz for Theoretical Physics, Leiden University, 271, Niels Bohrweg 2 Leiden, NL 2333 CA, The Netherlands
Paul M. Chaikin: Center for Soft Matter Research, New York University, 4 Washington Place, New York, New York 10003, USA

Nature, 2010, vol. 468, issue 7326, 947-951

Abstract: Pleating crystals A hexagonal lattice can be persuaded to tile a curved surface by the introduction of alternative shapes or 'topological defects' — such as heptagons and pentagons — as in the well-known 'buckyball' with its 20 hexagons and 12 pentagons. This paper reports a previously unknown type of defect that accommodates curvature in the same way as fabric pleats. Defects of this type, uncharged grain boundaries that vanish on the surface, can be observed on the negatively curved surfaces of stretched colloidal crystals. These findings will facilitate the exploration of general theories of defects in curved spaces, the engineering of curved structures and novel methods for soft lithography and directed self-assembly.

Date: 2010
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DOI: 10.1038/nature09620

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