Catalytic functionalization of unactivated primary C–H bonds directed by an alcohol

Eric M. Simmons and John F. Hartwig ()
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Eric M. Simmons: University of Illinois
John F. Hartwig: University of Illinois

Nature, 2012, vol. 483, issue 7387, 70-73

Abstract: The combination of an iridium-phenanthroline catalyst and a dihydridosilane reagent leads to the site-selective functionalization of primary C–H bonds that are proximal to a hydroxyl group.

Date: 2012
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DOI: 10.1038/nature10785

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