Asymmetric spiroacetalization catalysed by confined Brønsted acids

Ilija Čorić and Benjamin List ()
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Ilija Čorić: Max-Planck-Institut für Kohlenforschung, Kaiser-Wilhelm-Platz 1, 45470 Mülheim an der Ruhr, Germany
Benjamin List: Max-Planck-Institut für Kohlenforschung, Kaiser-Wilhelm-Platz 1, 45470 Mülheim an der Ruhr, Germany

Nature, 2012, vol. 483, issue 7389, 315-319

Abstract: Spiroacetals are found in a broad range of biologically active compounds, including small insect pheromones and more complex macrocycles; a confined imidodiphosphoric-acid catalyst is now reported that is able to facilitate the stereoselective synthesis of small, unfunctionalized spiroacetals.

Date: 2012
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DOI: 10.1038/nature10932

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