Dicalcium nitride as a two-dimensional electride with an anionic electron layer

Kimoon Lee, Sung Wng Kim, Yoshitake Toda, Satoru Matsuishi and Hideo Hosono ()
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Kimoon Lee: Frontier Research Center, Tokyo Institute of Technology, 4259 Nagatsuta, Midori-ku, Yokohama 226-8503, Japan
Sung Wng Kim: Frontier Research Center, Tokyo Institute of Technology, 4259 Nagatsuta, Midori-ku, Yokohama 226-8503, Japan
Yoshitake Toda: Frontier Research Center, Tokyo Institute of Technology, 4259 Nagatsuta, Midori-ku, Yokohama 226-8503, Japan
Satoru Matsuishi: Materials and Structures Laboratory, Tokyo Institute of Technology, 4259 Nagatsuta, Midori-ku, Yokohama 226-8503, Japan
Hideo Hosono: Frontier Research Center, Tokyo Institute of Technology, 4259 Nagatsuta, Midori-ku, Yokohama 226-8503, Japan

Nature, 2013, vol. 494, issue 7437, 336-340

Abstract: The ionic crystal Ca2N is shown to be an electride in terms of [Ca2N]+·e−, with diffusive two-dimensional transport in dense electron layers.

Date: 2013
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DOI: 10.1038/nature11812

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