Metal-free oxidation of aromatic carbon–hydrogen bonds through a reverse-rebound mechanism

Changxia Yuan, Yong Liang, Taylor Hernandez, Adrian Berriochoa, Kendall N. Houk and Dionicio Siegel ()
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Changxia Yuan: University of Texas at Austin
Yong Liang: University of California
Taylor Hernandez: University of Texas at Austin
Adrian Berriochoa: University of Texas at Austin
Kendall N. Houk: University of California
Dionicio Siegel: University of Texas at Austin

Nature, 2013, vol. 499, issue 7457, 192-196

Abstract: Phthaloyl peroxide functions as a selective oxidant of C–H bonds in the transformation of arenes to phenols under mild conditions, in a reaction that is compatible with a wide array of functional groups.

Date: 2013
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DOI: 10.1038/nature12284

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