Catalytic conversion of nitrogen to ammonia by an iron model complex

John S. Anderson, Jonathan Rittle and Jonas C. Peters ()
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John S. Anderson: California Institute of Technology
Jonathan Rittle: California Institute of Technology
Jonas C. Peters: California Institute of Technology

Nature, 2013, vol. 501, issue 7465, 84-87

Abstract: Catalysis of the reduction of nitrogen to ammonia under mild conditions by a tris(phosphine)borane-supported iron complex indicates that a single iron site may be capable of stabilizing the various NxHy intermediates generated during catalytic ammonia formation.

Date: 2013
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DOI: 10.1038/nature12435

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