Asymmetric synthesis from terminal alkenes by cascades of diboration and cross-coupling

Scott N. Mlynarski, Christopher H. Schuster and James P. Morken ()
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Scott N. Mlynarski: Merkert Chemistry Center, Boston College
Christopher H. Schuster: Merkert Chemistry Center, Boston College
James P. Morken: Merkert Chemistry Center, Boston College

Nature, 2014, vol. 505, issue 7483, 386-390

Abstract: A single-flask, catalytic enantioselective conversion of terminal alkenes into a number of chiral products is described: this tandem diboration/cross-coupling reaction works on a broad range of substrates, requires small amounts of commercially available catalysts, and provides products in high yield and high selectivity.

Date: 2014
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DOI: 10.1038/nature12781

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