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Tracking excited-state charge and spin dynamics in iron coordination complexes

Wenkai Zhang, Roberto Alonso-Mori, Uwe Bergmann, Christian Bressler, Matthieu Chollet, Andreas Galler, Wojciech Gawelda, Ryan G. Hadt, Robert W. Hartsock, Thomas Kroll, Kasper S. Kjær, Katharina Kubiček, Henrik T. Lemke, Huiyang W. Liang, Drew A. Meyer, Martin M. Nielsen, Carola Purser, Joseph S. Robinson, Edward I. Solomon, Zheng Sun, Dimosthenis Sokaras, Tim B. van Driel, György Vankó, Tsu-Chien Weng, Diling Zhu and Kelly J. Gaffney ()
Additional contact information
Wenkai Zhang: PULSE Institute, SLAC National Accelerator Laboratory, Stanford University
Roberto Alonso-Mori: LCLS, SLAC National Accelerator Laboratory
Uwe Bergmann: LCLS, SLAC National Accelerator Laboratory
Christian Bressler: European XFEL, D-22761 Hamburg, Germany
Matthieu Chollet: LCLS, SLAC National Accelerator Laboratory
Andreas Galler: European XFEL, D-22761 Hamburg, Germany
Wojciech Gawelda: European XFEL, D-22761 Hamburg, Germany
Ryan G. Hadt: Stanford University
Robert W. Hartsock: PULSE Institute, SLAC National Accelerator Laboratory, Stanford University
Thomas Kroll: Stanford University
Kasper S. Kjær: Centre for Molecular Movies, Niels Bohr Institute, University of Copenhagen, DK-2100 Copenhagen, Denmark
Katharina Kubiček: Max Planck Institute for Biophysical Chemistry, 37077 Göttingen, Germany
Henrik T. Lemke: LCLS, SLAC National Accelerator Laboratory
Huiyang W. Liang: PULSE Institute, SLAC National Accelerator Laboratory, Stanford University
Drew A. Meyer: PULSE Institute, SLAC National Accelerator Laboratory, Stanford University
Martin M. Nielsen: Centre for Molecular Movies, Technical University of Denmark, DK-2800 Lyngby, Denmark
Carola Purser: PULSE Institute, SLAC National Accelerator Laboratory, Stanford University
Joseph S. Robinson: LCLS, SLAC National Accelerator Laboratory
Edward I. Solomon: Stanford University
Zheng Sun: PULSE Institute, SLAC National Accelerator Laboratory, Stanford University
Dimosthenis Sokaras: SSRL, SLAC National Accelerator Laboratory
Tim B. van Driel: Centre for Molecular Movies, Technical University of Denmark, DK-2800 Lyngby, Denmark
György Vankó: Wigner Research Centre for Physics, Hungarian Academy of Sciences, H-1525 Budapest, Hungary
Tsu-Chien Weng: SSRL, SLAC National Accelerator Laboratory
Diling Zhu: LCLS, SLAC National Accelerator Laboratory
Kelly J. Gaffney: PULSE Institute, SLAC National Accelerator Laboratory, Stanford University

Nature, 2014, vol. 509, issue 7500, 345-348

Abstract: Femtosecond resolution X-ray fluorescence spectroscopy is shown to track the charge and spin dynamics triggered when an iron coordination complex is excited by light, and establishes the critical role of intermediate spin states in the de-excitation process.

Date: 2014
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DOI: 10.1038/nature13252

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