Carbon–carbon bond cleavage and rearrangement of benzene by a trinuclear titanium hydride

Shaowei Hu, Takanori Shima and Zhaomin Hou ()
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Shaowei Hu: Advanced Catalysis Research Group, RIKEN Center for Sustainable Resource Science, 2-1 Hirosawa, Wako, Saitama 351-0198, Japan
Takanori Shima: Advanced Catalysis Research Group, RIKEN Center for Sustainable Resource Science, 2-1 Hirosawa, Wako, Saitama 351-0198, Japan
Zhaomin Hou: Advanced Catalysis Research Group, RIKEN Center for Sustainable Resource Science, 2-1 Hirosawa, Wako, Saitama 351-0198, Japan

Nature, 2014, vol. 512, issue 7515, 413-415

Abstract: A trinuclear titanium polyhydride complex can be used to cleave carbon–carbon bonds in benzene and transform the benzene ring, suggesting that multinuclear titanium hydrides could be used to activate aromatic molecules.

Date: 2014
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DOI: 10.1038/nature13624

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