Identification of an iridium-containing compound with a formal oxidation state of IX

Guanjun Wang, Mingfei Zhou (), James T. Goettel, Gary J. Schrobilgen (), Jing Su, Jun Li, Tobias Schlöder and Sebastian Riedel ()
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Guanjun Wang: Collaborative Innovation Center of Chemistry for Energy Materials, Shanghai Key Laboratory of Molecular Catalysts and Innovative Materials, Fudan University
Mingfei Zhou: Collaborative Innovation Center of Chemistry for Energy Materials, Shanghai Key Laboratory of Molecular Catalysts and Innovative Materials, Fudan University
James T. Goettel: McMaster University, 1280 Main Street West, Hamilton, Ontario L8S 4M1, Canada
Gary J. Schrobilgen: McMaster University, 1280 Main Street West, Hamilton, Ontario L8S 4M1, Canada
Jing Su: Tsinghua University, Beijing 100084, China
Jun Li: Tsinghua University, Beijing 100084, China
Tobias Schlöder: Institut für Anorganische und Analytische Chemie, Albert-Ludwigs Universität Freiburg, Albertstrasse 21, D-79104 Freiburg im Breisgau, Germany
Sebastian Riedel: Institut für Anorganische und Analytische Chemie, Albert-Ludwigs Universität Freiburg, Albertstrasse 21, D-79104 Freiburg im Breisgau, Germany

Nature, 2014, vol. 514, issue 7523, 475-477

Abstract: The tetrahedral iridium tetroxide cation [IrO4]+, which has an iridium 5d0 valence electron configuration and a formal oxidation state of IX, is generated in the gas phase, identified by infrared photodissociation spectroscopy, and predicted, by quantum chemical calculations, to be the most stable of all possible [IrO4]+ isomers.

Date: 2014
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DOI: 10.1038/nature13795

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