High-value alcohols and higher-oxidation-state compounds by catalytic Z-selective cross-metathesis

Ming Joo Koh, R. Kashif M. Khan, Sebastian Torker, Miao Yu, Malte S. Mikus and Amir H. Hoveyda ()
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Ming Joo Koh: Merkert Chemistry Center, Boston College
R. Kashif M. Khan: Merkert Chemistry Center, Boston College
Sebastian Torker: Merkert Chemistry Center, Boston College
Miao Yu: Merkert Chemistry Center, Boston College
Malte S. Mikus: Merkert Chemistry Center, Boston College
Amir H. Hoveyda: Merkert Chemistry Center, Boston College

Nature, 2015, vol. 517, issue 7533, 181-186

Abstract: A ruthenium–disulfide catalyst is presented that is effective in generating compounds of medical and industrial utility (alcohols that contain a phenol, an aldehyde, or a carboxylic acid) by room-temperature, inexpensive, high-yielding cross-metathesis.

Date: 2015
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DOI: 10.1038/nature14061

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