Metal-catalysed azidation of tertiary C–H bonds suitable for late-stage functionalization

Ankit Sharma and John F. Hartwig ()
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Ankit Sharma: University of California
John F. Hartwig: University of California

Nature, 2015, vol. 517, issue 7536, 600-604

Abstract: Most currently used catalysts for the amination of C–H bonds are ill suited to the functionalization of complex molecules; here it is shown that a mild, selective, iron-catalysed azidation of tertiary C–H bonds is suitable for the amination of complex molecules containing a range of functional groups.

Date: 2015
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DOI: 10.1038/nature14127

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