Ligand-enabled meta-C–H activation using a transient mediator

Xiao-Chen Wang, Wei Gong, Li-Zhen Fang, Ru-Yi Zhu, Suhua Li, Keary M. Engle and Jin-Quan Yu ()
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Xiao-Chen Wang: The Scripps Research Institute, 10550 N. Torrey Pines Road, La Jolla, California 92037, USA
Wei Gong: The Scripps Research Institute, 10550 N. Torrey Pines Road, La Jolla, California 92037, USA
Li-Zhen Fang: The Scripps Research Institute, 10550 N. Torrey Pines Road, La Jolla, California 92037, USA
Ru-Yi Zhu: The Scripps Research Institute, 10550 N. Torrey Pines Road, La Jolla, California 92037, USA
Suhua Li: The Scripps Research Institute, 10550 N. Torrey Pines Road, La Jolla, California 92037, USA
Keary M. Engle: The Scripps Research Institute, 10550 N. Torrey Pines Road, La Jolla, California 92037, USA
Jin-Quan Yu: The Scripps Research Institute, 10550 N. Torrey Pines Road, La Jolla, California 92037, USA

Nature, 2015, vol. 519, issue 7543, 334-338

Abstract: A combination of norbornene and pyridine-type ligand enables commonly used ortho-directing groups to direct meta-C–H activation with palladium catalysts.

Date: 2015
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DOI: 10.1038/nature14214

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