Square ice in graphene nanocapillaries

G. Algara-Siller, O. Lehtinen, F. C. Wang, R. R. Nair, U. Kaiser (), H. A. Wu (), A. K. Geim and I. V. Grigorieva ()
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G. Algara-Siller: Central Facility for Electron Microscopy, Group of Electron Microscopy of Materials Science, University of Ulm, 89081 Ulm, Germany
O. Lehtinen: Central Facility for Electron Microscopy, Group of Electron Microscopy of Materials Science, University of Ulm, 89081 Ulm, Germany
F. C. Wang: Chinese Academy of Sciences Key Laboratory of Mechanical Behavior and Design of Materials, University of Science and Technology of China
R. R. Nair: School of Physics and Astronomy, University of Manchester, Manchester M13 9PL, UK
U. Kaiser: Central Facility for Electron Microscopy, Group of Electron Microscopy of Materials Science, University of Ulm, 89081 Ulm, Germany
H. A. Wu: Chinese Academy of Sciences Key Laboratory of Mechanical Behavior and Design of Materials, University of Science and Technology of China
A. K. Geim: School of Physics and Astronomy, University of Manchester, Manchester M13 9PL, UK
I. V. Grigorieva: School of Physics and Astronomy, University of Manchester, Manchester M13 9PL, UK

Nature, 2015, vol. 519, issue 7544, 443-445

Abstract: The structure of the low-dimensional water confined in hydrophobic pores is shown, using electron microscopy and supported by molecular dynamics simulations, to be ‘square ice’, which does not have the conventional tetrahedral hydrogen bonding.

Date: 2015
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DOI: 10.1038/nature14295

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