Binding of dinitrogen to an iron–sulfur–carbon site

Ilija Čorić, Brandon Q. Mercado, Eckhard Bill, David J. Vinyard and Patrick L. Holland ()
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Ilija Čorić: Yale University
Brandon Q. Mercado: Yale University
Eckhard Bill: Max Planck Institute for Chemical Energy Conversion
David J. Vinyard: Yale University
Patrick L. Holland: Yale University

Nature, 2015, vol. 526, issue 7571, 96-99

Abstract: A synthetic complex with a sulfur-rich coordination sphere is described that, upon reduction, breaks an Fe–S bond and binds N2, providing a model for the iron–molybdenum cofactor used by nitrogenase enzymes to produce ammonia.

Date: 2015
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Persistent link: https://EconPapers.repec.org/RePEc:nat:nature:v:526:y:2015:i:7571:d:10.1038_nature15246

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DOI: 10.1038/nature15246

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