Organometallic palladium reagents for cysteine bioconjugation

Ekaterina V. Vinogradova, Chi Zhang, Alexander M. Spokoyny, Bradley L. Pentelute () and Stephen L. Buchwald ()
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Ekaterina V. Vinogradova: Massachusetts Institute of Technology
Chi Zhang: Massachusetts Institute of Technology
Alexander M. Spokoyny: Massachusetts Institute of Technology
Bradley L. Pentelute: Massachusetts Institute of Technology
Stephen L. Buchwald: Massachusetts Institute of Technology

Nature, 2015, vol. 526, issue 7575, 687-691

Abstract: Palladium(ii) complexes can be used in efficient and highly selective cysteine conjugation reactions that are rapid and robust, and the resulting aryl bioconjugates are stable towards acids, bases, oxidants and external thiol nucleophiles.

Date: 2015
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DOI: 10.1038/nature15739

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