Rhodium-catalysed syn-carboamination of alkenes via a transient directing group

Tiffany Piou and Tomislav Rovis ()
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Tiffany Piou: Colorado State University
Tomislav Rovis: Colorado State University

Nature, 2015, vol. 527, issue 7576, 86-90

Abstract: Chemical methods for adding carbon-based or nitrogen-based functional groups to alkenes are well established, but strategies for adding both to the same double bond have limitations; here, a method for the carboamination of alkenes at the same double bond is described.

Date: 2015
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DOI: 10.1038/nature15691

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