Methane storage in flexible metal–organic frameworks with intrinsic thermal management

Jarad A. Mason, Julia Oktawiec, Mercedes K. Taylor, Matthew R. Hudson, Julien Rodriguez, Jonathan E. Bachman, Miguel I. Gonzalez, Antonio Cervellino, Antonietta Guagliardi, Craig M. Brown, Philip L. Llewellyn, Norberto Masciocchi and Jeffrey R. Long ()
Additional contact information
Jarad A. Mason: University of California
Julia Oktawiec: University of California
Mercedes K. Taylor: University of California
Matthew R. Hudson: Center for Neutron Research, National Institute of Standards and Technology
Julien Rodriguez: Aix-Marseille University, CNRS Laboratoire MADIREL (UMR 7246), Centre de Saint Jérôme
Jonathan E. Bachman: University of California
Miguel I. Gonzalez: University of California
Antonio Cervellino: Laboratory for Synchrotron Radiation – Condensed Matter, Swiss Light Source, Paul Scherrer Institute
Antonietta Guagliardi: Istituto di Cristallografia, Consiglio Nazionale delle Ricerche, and To.Sca.Lab.
Craig M. Brown: Center for Neutron Research, National Institute of Standards and Technology
Philip L. Llewellyn: Aix-Marseille University, CNRS Laboratoire MADIREL (UMR 7246), Centre de Saint Jérôme
Norberto Masciocchi: Università dell’Insubria, and To.Sca.Lab
Jeffrey R. Long: University of California

Nature, 2015, vol. 527, issue 7578, 357-361

Abstract: Two flexible metal-organic frameworks are presented as solid adsorbents for methane that undergo reversible phase transitions at specific methane pressures, enabling greater storage capacities of usable methane than have been achieved previously, while also providing internal heat management of the system.

Date: 2015
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DOI: 10.1038/nature15732

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