Extra adsorption and adsorbate superlattice formation in metal-organic frameworks

Hae Sung Cho, Hexiang Deng, Keiichi Miyasaka, Zhiyue Dong, Minhyung Cho, Alexander V. Neimark, Jeung Ku Kang, Omar M. Yaghi () and Osamu Terasaki ()
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Hae Sung Cho: Graduate School of Energy, Environment, Water and Sustainability, WCU/BK21Plus, KAIST
Hexiang Deng: Key Laboratory of Biomedical Polymers-Ministry of Education, College of Chemistry and Molecular Sciences, Wuhan University
Keiichi Miyasaka: Graduate School of Energy, Environment, Water and Sustainability, WCU/BK21Plus, KAIST
Zhiyue Dong: Key Laboratory of Biomedical Polymers-Ministry of Education, College of Chemistry and Molecular Sciences, Wuhan University
Minhyung Cho: Graduate School of Energy, Environment, Water and Sustainability, WCU/BK21Plus, KAIST
Alexander V. Neimark: Rutgers University
Jeung Ku Kang: Graduate School of Energy, Environment, Water and Sustainability, WCU/BK21Plus, KAIST
Omar M. Yaghi: Graduate School of Energy, Environment, Water and Sustainability, WCU/BK21Plus, KAIST
Osamu Terasaki: Graduate School of Energy, Environment, Water and Sustainability, WCU/BK21Plus, KAIST

Nature, 2015, vol. 527, issue 7579, 503-507

Abstract: Metal-organic frameworks have a porous structure that has useful applications in gas adsorption; here, small-angle X-ray scattering is used to visualize the process of adsorption as gas pressure increases, revealing that adsorbate molecules interact across pore walls in a way that allows extra adsorbate domains to be created in the framework and to form superlattices, before the adsorbate settles down into a more uniform distribution.

Date: 2015
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DOI: 10.1038/nature15734

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