Nineteen-step total synthesis of (+)-phorbol

Shuhei Kawamura, Hang Chu, Jakob Felding and Phil S. Baran ()
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Shuhei Kawamura: The Scripps Research Institute
Hang Chu: The Scripps Research Institute
Jakob Felding: Front End Innovation
Phil S. Baran: The Scripps Research Institute

Nature, 2016, vol. 532, issue 7597, 90-93

Abstract: Enantiospecific total synthesis of (+)-phorbol in only 19 steps from the abundant monoterpene (+)-3-carene is demonstrated using a two-phase terpene synthesis strategy.

Date: 2016
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DOI: 10.1038/nature17153

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