Asymmetric catalytic formation of quaternary carbons by iminium ion trapping of radicals

John J. Murphy, David Bastida, Suva Paria, Maurizio Fagnoni and Paolo Melchiorre ()
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John J. Murphy: Institute of Chemical Research of Catalonia (ICIQ), Barcelona Institute of Science and Technology
David Bastida: Institute of Chemical Research of Catalonia (ICIQ), Barcelona Institute of Science and Technology
Suva Paria: Institute of Chemical Research of Catalonia (ICIQ), Barcelona Institute of Science and Technology
Maurizio Fagnoni: Photogreen Laboratory, University of Pavia
Paolo Melchiorre: Institute of Chemical Research of Catalonia (ICIQ), Barcelona Institute of Science and Technology

Nature, 2016, vol. 532, issue 7598, 218-222

Abstract: A combination of photoredox and asymmetric organic catalysis enables enantioselective radical conjugate additions to β,β-disubstituted cyclic enones to construct quaternary carbon stereocentres with high fidelity.

Date: 2016
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DOI: 10.1038/nature17438

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