The pentadehydro-Diels–Alder reaction

Teng Wang, Rajasekhar Reddy Naredla, Severin K. Thompson and Thomas R. Hoye ()
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Teng Wang: University of Minnesota
Rajasekhar Reddy Naredla: University of Minnesota
Severin K. Thompson: University of Minnesota
Thomas R. Hoye: University of Minnesota

Nature, 2016, vol. 532, issue 7600, 484-488

Abstract: A modification to the classic Diels–Alder [4 + 2] cycloaddition reaction, termed the pentadehydro-Diels–Alder reaction, is reported; this reaction generates a highly reactive intermediate, an α,3-dehydrotoluene, that can be captured using various trapping agents to produce structurally diverse products.

Date: 2016
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DOI: 10.1038/nature17429

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