Iron(III)-catalysed carbonyl–olefin metathesis

Jacob R. Ludwig, Paul M. Zimmerman, Joseph B. Gianino and Corinna S. Schindler ()
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Jacob R. Ludwig: University of Michigan, Willard Henry Dow Laboratory, 930 North University Avenue
Paul M. Zimmerman: University of Michigan, Willard Henry Dow Laboratory, 930 North University Avenue
Joseph B. Gianino: University of Michigan, Willard Henry Dow Laboratory, 930 North University Avenue
Corinna S. Schindler: University of Michigan, Willard Henry Dow Laboratory, 930 North University Avenue

Nature, 2016, vol. 533, issue 7603, 374-379

Abstract: The olefin metathesis reaction of two unsaturated substrates is one of the most powerful carbon–carbon-bond-forming reactions in organic chemistry; here, a catalytic carbonyl–olefin ring-closing metathesis reaction is demonstrated that uses iron, an abundant and environmentally benign metal, as a catalyst.

Date: 2016
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DOI: 10.1038/nature17432

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