Synergistic, ultrafast mass storage and removal in artificial mixed conductors

Chia-Chin Chen, Lijun Fu and Joachim Maier ()
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Chia-Chin Chen: Max Planck Institute for Solid State Research, Heisenbergstraße 1
Lijun Fu: Max Planck Institute for Solid State Research, Heisenbergstraße 1
Joachim Maier: Max Planck Institute for Solid State Research, Heisenbergstraße 1

Nature, 2016, vol. 536, issue 7615, 159-164

Abstract: Abstract Mixed conductors—single phases that conduct electronically and ionically—enable stoichiometric variations in a material and, therefore, mass storage and redistribution, for example, in battery electrodes. We have considered how such properties may be achieved synergistically in solid two-phase systems, forming artificial mixed conductors. Previously investigated composites suffered from poor kinetics and did not allow for a clear determination of such stoichiometric variations. Here we show, using electrochemical and chemical methods, that a melt-processed composite of the ‘super-ionic’ conductor RbAg4I5 and the electronic conductor graphite exhibits both a remarkable silver excess and a silver deficiency, similar to those found in single-phase mixed conductors, even though such behaviour is not possible in the individual phases. Furthermore, the kinetics of silver uptake and release is very fast. Evaluating the upper limit of the relaxation time set by interfacial ambipolar diffusion reveals chemical diffusion coefficients that are even higher than those achieved for sodium chloride in bulk liquid water. These results could potentially stimulate systematic research into powerful, even mesoscopic, artificial mixed conductors.

Date: 2016
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DOI: 10.1038/nature19078

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