Metallaphotoredox-catalysed sp3–sp3 cross-coupling of carboxylic acids with alkyl halides

Craig P. Johnston, Russell T. Smith, Simon Allmendinger and David W. C. MacMillan ()
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Craig P. Johnston: Merck Center for Catalysis at Princeton University
Russell T. Smith: Merck Center for Catalysis at Princeton University
Simon Allmendinger: Merck Center for Catalysis at Princeton University
David W. C. MacMillan: Merck Center for Catalysis at Princeton University

Nature, 2016, vol. 536, issue 7616, 322-325

Abstract: The long-sought direct formation of a bond between two sp3-hybridized carbon atoms is achieved by the merger of photoredox and nickel catalysis using only simple carboxylic acids and alkyl halides as starting materials.

Date: 2016
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DOI: 10.1038/nature19056

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