Metal–organic frameworks as selectivity regulators for hydrogenation reactions

Meiting Zhao, Kuo Yuan, Yun Wang, Guodong Li (), Jun Guo, Lin Gu, Wenping Hu, Huijun Zhao () and Zhiyong Tang ()
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Meiting Zhao: Chinese Academy of Sciences (CAS) Key Laboratory of Nanosystem and Hierarchy Fabrication, CAS Center for Excellence in Nanoscience, National Center for Nanoscience and Technology
Kuo Yuan: Chinese Academy of Sciences (CAS) Key Laboratory of Nanosystem and Hierarchy Fabrication, CAS Center for Excellence in Nanoscience, National Center for Nanoscience and Technology
Yun Wang: Centre for Clean Environment and Energy, Gold Coast Campus, Griffith University
Guodong Li: Chinese Academy of Sciences (CAS) Key Laboratory of Nanosystem and Hierarchy Fabrication, CAS Center for Excellence in Nanoscience, National Center for Nanoscience and Technology
Jun Guo: Chinese Academy of Sciences (CAS) Key Laboratory of Nanosystem and Hierarchy Fabrication, CAS Center for Excellence in Nanoscience, National Center for Nanoscience and Technology
Lin Gu: Institute of Physics, Chinese Academy of Sciences
Wenping Hu: School of Science, Tianjin University
Huijun Zhao: Centre for Clean Environment and Energy, Gold Coast Campus, Griffith University
Zhiyong Tang: Chinese Academy of Sciences (CAS) Key Laboratory of Nanosystem and Hierarchy Fabrication, CAS Center for Excellence in Nanoscience, National Center for Nanoscience and Technology

Nature, 2016, vol. 539, issue 7627, 76-80

Abstract: The flavouring, perfume and pharmaceutical industries rely on the selective hydrogenation of α,β-unsaturated aldehydes to generate unsaturated alcohols; here, a new type of highly selective catalyst is described in which platinum nanoparticles are sandwiched between a core and a shell of a metal−organic framework.

Date: 2016
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DOI: 10.1038/nature19763

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