Catalytic alkylation of remote C–H bonds enabled by proton-coupled electron transfer

Gilbert J. Choi, Qilei Zhu, David C. Miller, Carol J. Gu and Robert R. Knowles ()
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Gilbert J. Choi: Princeton University
Qilei Zhu: Princeton University
David C. Miller: Princeton University
Carol J. Gu: Princeton University
Robert R. Knowles: Princeton University

Nature, 2016, vol. 539, issue 7628, 268-271

Abstract: Catalytic alkylation of C–H bonds is achieved via homolysis of N–H bonds of N-alkyl amides through proton-coupled electron transfer.

Date: 2016
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DOI: 10.1038/nature19811

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