Molybdenum chloride catalysts for Z-selective olefin metathesis reactions

Ming Joo Koh, Thach T. Nguyen, Jonathan K. Lam, Sebastian Torker, Jakub Hyvl, Richard R. Schrock and Amir H. Hoveyda ()
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Ming Joo Koh: Merkert Chemistry Center, Boston College
Thach T. Nguyen: Merkert Chemistry Center, Boston College
Jonathan K. Lam: Massachusetts Institute of Technology
Sebastian Torker: Merkert Chemistry Center, Boston College
Jakub Hyvl: Massachusetts Institute of Technology
Richard R. Schrock: Massachusetts Institute of Technology
Amir H. Hoveyda: Merkert Chemistry Center, Boston College

Nature, 2017, vol. 542, issue 7639, 80-85

Abstract: Substitution of a ligand in molybdenum-based complexes enables typically inert hexafluorobutene to participate in Z-selective olefin cross-metathesis reactions.

Date: 2017
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DOI: 10.1038/nature21043

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