Decarboxylative alkenylation

Jacob T. Edwards, Rohan R. Merchant, Kyle S. McClymont, Kyle W. Knouse, Tian Qin, Lara R. Malins, Benjamin Vokits, Scott A. Shaw, Deng-Hui Bao, Fu-Liang Wei, Ting Zhou, Martin D. Eastgate and Phil S. Baran ()
Additional contact information
Jacob T. Edwards: The Scripps Research Institute
Rohan R. Merchant: The Scripps Research Institute
Kyle S. McClymont: The Scripps Research Institute
Kyle W. Knouse: The Scripps Research Institute
Tian Qin: The Scripps Research Institute
Lara R. Malins: The Scripps Research Institute
Benjamin Vokits: Discovery Chemistry, Bristol-Myers Squibb
Scott A. Shaw: Discovery Chemistry, Bristol-Myers Squibb
Deng-Hui Bao: Asymchem Life Science (Tianjin), Tianjin Economic-technological Development Zone
Fu-Liang Wei: Asymchem Life Science (Tianjin), Tianjin Economic-technological Development Zone
Ting Zhou: Asymchem Life Science (Tianjin), Tianjin Economic-technological Development Zone
Martin D. Eastgate: Chemical Development, Bristol-Myers Squibb, One Squibb Drive
Phil S. Baran: The Scripps Research Institute

Nature, 2017, vol. 545, issue 7653, 213-218

Abstract: Starting with alkyl carboxylic acids, a simple olefin synthesis using any substitution pattern or geometry, based on amide-bond synthesis with nickel- or iron-based catalysis, is described.

Date: 2017
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DOI: 10.1038/nature22307

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