Nitrogen reduction and functionalization by a multimetallic uranium nitride complex

Marta Falcone, Lucile Chatelain, Rosario Scopelliti, Ivica Živković and Marinella Mazzanti ()
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Marta Falcone: Institut des Sciences et Ingénierie Chimiques, École Polytechnique Fédérale de Lausanne (EPFL)
Lucile Chatelain: Institut des Sciences et Ingénierie Chimiques, École Polytechnique Fédérale de Lausanne (EPFL)
Rosario Scopelliti: Institut des Sciences et Ingénierie Chimiques, École Polytechnique Fédérale de Lausanne (EPFL)
Ivica Živković: Laboratory for Quantum Magnetism, Institute of Physics, École Polytechnique Fédérale de Lausanne (EPFL)
Marinella Mazzanti: Institut des Sciences et Ingénierie Chimiques, École Polytechnique Fédérale de Lausanne (EPFL)

Nature, 2017, vol. 547, issue 7663, 332-335

Abstract: A complex containing two uranium ions and three potassium ions, held together by a nitride group and a flexible molecular framework, can reduce and functionalize N2 under mild conditions.

Date: 2017
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DOI: 10.1038/nature23279

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