A spin transition mechanism for cooperative adsorption in metal–organic frameworks

Douglas A. Reed, Benjamin K. Keitz, Julia Oktawiec, Jarad A. Mason, Tomče Runčevski, Dianne J. Xiao, Lucy E. Darago, Valentina Crocellà, Silvia Bordiga and Jeffrey R. Long ()
Additional contact information
Douglas A. Reed: University of California
Benjamin K. Keitz: University of California
Julia Oktawiec: University of California
Jarad A. Mason: University of California
Tomče Runčevski: University of California
Dianne J. Xiao: University of California
Lucy E. Darago: University of California
Valentina Crocellà: NIS and INSTM Centre of Reference, University of Turin
Silvia Bordiga: NIS and INSTM Centre of Reference, University of Turin
Jeffrey R. Long: University of California

Nature, 2017, vol. 550, issue 7674, 96-100

Abstract: Metal–organic frameworks that undergo a cooperative spin transition at neighbouring metal centres upon coordination to CO exhibit large CO separation capacities with only small changes in temperature.

Date: 2017
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DOI: 10.1038/nature23674

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