Ligand-accelerated non-directed C–H functionalization of arenes

Peng Wang, Pritha Verma, Guoqin Xia, Jun Shi, Jennifer X. Qiao, Shiwei Tao, Peter T. W. Cheng, Michael A. Poss, Marcus E. Farmer, Kap-Sun Yeung and Jin-Quan Yu ()
Additional contact information
Peng Wang: The Scripps Research Institute
Pritha Verma: The Scripps Research Institute
Guoqin Xia: The Scripps Research Institute
Jun Shi: Discovery Chemistry, Bristol-Myers Squibb Company
Jennifer X. Qiao: Discovery Chemistry, Bristol-Myers Squibb Company
Shiwei Tao: Discovery Chemistry, Bristol-Myers Squibb Company
Peter T. W. Cheng: Discovery Chemistry, Bristol-Myers Squibb Company
Michael A. Poss: Discovery Chemistry, Bristol-Myers Squibb Company
Marcus E. Farmer: The Scripps Research Institute
Kap-Sun Yeung: Discovery Chemistry, Bristol-Myers Squibb Company
Jin-Quan Yu: The Scripps Research Institute

Nature, 2017, vol. 551, issue 7681, 489-493

Abstract: Using a ligand as a promoter enhances the reactivity of the palladium catalyst in non-directed C–H functionalization of arenes, enabling the arene to be used as the limiting reagent.

Date: 2017
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DOI: 10.1038/nature24632

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