Site-selective and stereoselective functionalization of non-activated tertiary C–H bonds

Kuangbiao Liao, Thomas C. Pickel, Vyacheslav Boyarskikh, John Bacsa, Djamaladdin G. Musaev and Huw M. L. Davies ()
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Kuangbiao Liao: Emory University
Thomas C. Pickel: Emory University
Vyacheslav Boyarskikh: Emory University
John Bacsa: Emory University
Djamaladdin G. Musaev: Cherry L. Emerson Center for Scientific Computation, Emory University
Huw M. L. Davies: Emory University

Nature, 2017, vol. 551, issue 7682, 609-613

Abstract: The functionalization of specific inert C–H bonds avoids the need for functional groups in organic synthesis and here the challenges of this approach are overcome using a dirhodium catalyst that is capable of C–H bond site-selectivity.

Date: 2017
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DOI: 10.1038/nature24641

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