Generating carbyne equivalents with photoredox catalysis

Zhaofeng Wang, Ana G. Herraiz, Ana M. del Hoyo and Marcos G. Suero ()
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Zhaofeng Wang: Institute of Chemical Research of Catalonia (ICIQ), The Barcelona Institute of Science and Technology
Ana G. Herraiz: Institute of Chemical Research of Catalonia (ICIQ), The Barcelona Institute of Science and Technology
Ana M. del Hoyo: Institute of Chemical Research of Catalonia (ICIQ), The Barcelona Institute of Science and Technology
Marcos G. Suero: Institute of Chemical Research of Catalonia (ICIQ), The Barcelona Institute of Science and Technology

Nature, 2018, vol. 554, issue 7690, 86-91

Abstract: A photocatalytic strategy is described that generates diazomethyl radicals as direct equivalents of carbynes, which are often too reactive to use, enabling the functionalization of a range of medically useful compounds.

Date: 2018
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DOI: 10.1038/nature25185

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